Observation of the rotational spectra of CuI and AgI molecules generated by laser ablation in a pulsed-jet, Fourier-transform microwave spectrometer

Susan G. Batten، نويسنده , , Anna G. Ward، نويسنده , , A.C. Legon*، نويسنده ,

روزنامه با شماره پیاپی سال 2006

6

300

305

thenuclear hyperfine coupling constants c(63Cu) , centrifugal distortion constant D0 , 109Ag127I , 63Cu127I and 65Cu127I by analysis of its rotational spectrum. In the case of the two CuI isotopomers , c(65Cu) , The diatomic species CuI and AgI were produced by the reaction of metal atoms , Mbb(63Cu) and Mbb(65Cu) were also established.q 2005 Elsevier B.V. All rights reserved , iodine nuclearquadrupole coupling constant c(I) and iodine spin-rotation coupling constant Mbb(I) were determined with high precision for each of theisotopomers 107Ag127I , formed in situ by ablation of an appropriate metal rod , with methyl iodide entrained in argon. The rotational spectra of the MI species so produced were then observed with the aid of a pulsed-jet , Fourier-transform microwave spectrometer. The ground-state rotational constant B0

Journal of Molecular Structure

2006

Journal of Molecular Structure

845238