Title of article
Unexpected α-stereochemical outcomes of attempted β-glycosylations Original Research Article
Author/Authors
Feng Yang، نويسنده , , Hongmei He، نويسنده , , Yuguo Du، نويسنده , , Mujian Lü، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2002
Pages
5
From page
1165
To page
1169
Abstract
In an effort to prepare complex oligosaccharide derivatives, a series of unexpected α glycosides were predominantly formed in the presence of neighboring group participation using imidates or thioglycosides as glycosyl donors under standard glycosylation conditions. The observations are especially suitable in the case of α-(1→3) glycosidic bond formation.
Keywords
Neighboring group participation effects , Stereoselectivity , Oligosaccharide , Glycosylation
Journal title
Carbohydrate Research
Serial Year
2002
Journal title
Carbohydrate Research
Record number
963504
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