Title of article
Mechanism of the transition-metal-catalyzed mutarotation reaction of N-(p-chlorophenyl)-β-d-glucopyranosylamine in methanol Original Research Article
Author/Authors
Kazimiera Smiataczowa، نويسنده , , Jaros?aw Kosmalski، نويسنده , , Teresa Widernik، نويسنده , , Zygmunt Warnke، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2003
Pages
7
From page
969
To page
975
Abstract
Rate constants for the mutarotation reaction of N-(p-chlorophenyl)-β-d-glucopyranosylamine (NGlc) in methanol have been determined in the presence of transition metal chlorides (MCl2), at 25 °C. The activity of the metal ions catalyzing the α-pyranoside↔β-pyranoside interconversion has been found to increase in the following series: Mn2+
Keywords
N-(p-Chlorophenyl)-?-d-glucopyranosylamine , Methanol , Metal chlorides
Journal title
Carbohydrate Research
Serial Year
2003
Journal title
Carbohydrate Research
Record number
963725
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