Title of article
Synthesis and co-polymerization of an unsaturated 1,5-anhydro-d-fructose derivative Original Research Article
Author/Authors
Olaf Deppe، نويسنده , , Anke Glümer، نويسنده , , Shukun Yu، نويسنده , , Klaus Buchholz، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2004
Pages
6
From page
2077
To page
2082
Abstract
An unsaturated derivative, 3,6-di-O-acetyl-1,5-anhydro-4-deoxy-d-glycero-hex-3-enopyranos-2-ulose (3), was obtained via regioselective elimination and acetylation of monohydrated 1,5-anhydro-d-fructose (1) in a single step reaction. High yield (80%) was achieved without any dimeric by-products. Its co-polymerization to saccharide polymers was investigated with different commercial vinyl co-monomers. Co-polymers were obtained and characterized.
Keywords
Sugar derivatives , 1 , Unsaturated , Pyranoid enolone ester , 5-Anhydro-d-fructose , Radical polymerization , Saccharide polymers
Journal title
Carbohydrate Research
Serial Year
2004
Journal title
Carbohydrate Research
Record number
964176
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