Title of article
Regiochemistry of epoxide ring opening in methyl 2,3-anhydro-4-azido-4-deoxy-α- and β-l-lyxopyranosides
Author/Authors
Velimir Popsavin، نويسنده , , Goran Benedekovi?، نويسنده , , Mirjana Popsavin، نويسنده , , Bojana Sre?o، نويسنده , , Dejan Djokovi?، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2005
Pages
6
From page
1866
To page
1871
Abstract
Methyl 2,3-anhydro-4-O-methanesulfonyl-α-d-ribopyranoside (12) was prepared through a new six-step sequence starting from d-arabinose. Chemical behaviour of 12 was further studied under solvolytic conditions and in the presence of azide anion as a nucleophile. Factors governing the regiochemistry of epoxide ring opening are briefly discussed.
Keywords
Regioselectivity , Epoxide ring opening , Azido sugars , 2 , 3-Anhydro-lyxopyranosides , 3-Anhydro-ribopyranosides , 2
Journal title
Carbohydrate Research
Serial Year
2005
Journal title
Carbohydrate Research
Record number
964489
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