Title of article :
A theoretical analysis of the Ti(IV)-catalyzed glycoaminocyanation reaction
Author/Authors :
Elena Soriano، نويسنده , , José Marco-Contelles، نويسنده , , Hélène Ducatel، نويسنده , , Albert Nguyen van Nhien، نويسنده , , Denis Postel، نويسنده ,
Issue Information :
دوهفته نامه با شماره پیاپی سال 2008
Abstract :
The chelation of the Lewis acid Ti(OiPr)4 provides the necessary conformational control to induce π-facial selectivity on the cyanation process. The steric hindrance imposed by the α-substituent restrains the addition for l-amino acid derivatives.
Keywords :
Lewis acid , Titanium , Stereoselective reactions , DFT methodology
Journal title :
Carbohydrate Research
Journal title :
Carbohydrate Research
