Title of article
A theoretical analysis of the Ti(IV)-catalyzed glycoaminocyanation reaction
Author/Authors
Elena Soriano، نويسنده , , José Marco-Contelles، نويسنده , , Hélène Ducatel، نويسنده , , Albert Nguyen van Nhien، نويسنده , , Denis Postel، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2008
Pages
5
From page
1835
To page
1839
Abstract
The chelation of the Lewis acid Ti(OiPr)4 provides the necessary conformational control to induce π-facial selectivity on the cyanation process. The steric hindrance imposed by the α-substituent restrains the addition for l-amino acid derivatives.
Keywords
Lewis acid , Titanium , Stereoselective reactions , DFT methodology
Journal title
Carbohydrate Research
Serial Year
2008
Journal title
Carbohydrate Research
Record number
964839
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