Title of article
Pre-activation of fully acetylated dodecyl thioglycosides with BSP–Tf2O led to efficient glycosylation at low temperature Original Research Article
Author/Authors
Sang-Hyun Son، نويسنده , , Chiharu Tano، نويسنده , , Tetsuya Furuike، نويسنده , , Nobuo Sakairi، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2009
Pages
6
From page
285
To page
290
Abstract
Fully acetylated dodecyl thioglycosides were found to be useful as glycosyl donors by activation with 1-benzenesulfinyl piperidine (BSP) and triflic anhydride (Tf2O) at −78 °C. The glycosyl acceptor was added to the reaction mixture at the same temperature to furnish various disaccharide, including the protected Lewis a (Lea) trisaccharide, in good yields.
Keywords
Dodecyl thioglycosides , Glycosylation , 1-Dodecanethiol , Oligosaccharides
Journal title
Carbohydrate Research
Serial Year
2009
Journal title
Carbohydrate Research
Record number
965711
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