Title of article
Evidence of benzilic rearrangement during the electrochemical oxidation of d-glucose to d-glucaric acid
Author/Authors
Mathias Ibert، نويسنده , , Patrick Fuertès، نويسنده , , Nabyl Merbouh، نويسنده , , Christian Feasson، نويسنده , , Francis Marsais، نويسنده ,
Issue Information
دوهفته نامه با شماره پیاپی سال 2011
Pages
7
From page
512
To page
518
Abstract
During the course of the 2,2,6,6-tetramethyl-1-piperidinyloxy free radical-catalyzed electrochemical oxidation of d-glucose to d-glucaric acid a new side-product was observed. This compound was isolated and identified as a tricarboxylic acid of unique structure, which was named maribersonic acid. Its structure was proven by different experiments coupled with several analytical methods, and its appearance during the electrochemical oxidation of d-glucose was rationalized through a thorough study.
Keywords
Benzilic rearrangement , Tricarboxylic acid , Electrochemical oxidation , Maribersonic acid , TEMPO
Journal title
Carbohydrate Research
Serial Year
2011
Journal title
Carbohydrate Research
Record number
966881
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