Radioecological survey at selected sites hit by depleted uranium ammunitions during the 1999 Kosovo conflict

A field study, organised, coordinated and conducted under the responsibility of the United Nations Environment Programme ŽUNEP., took place in Kosovo in November 2000 to evaluate the level of depleted uranium ŽDU. released into the environment by the use of DU ammunition during the 1999 conflict. Representatives of six different scientific organisations took part in the mission and a total of approximately 350 samples were collected. During this field mission, the Italian National Environmental Protection Agency ŽANPA. collected water, soil, lichen and tree bark samples from different sites. The samples were analysed by -spectroscopy and in some cases by inductively coupled plasma-source mass spectrometry ŽICP-MS.. The 234U 238U and 235U 238U activity concentration ratios were used to distinguish natural from anthropogenic uranium. This paper reports the results obtained on these samples. All water samples had very low concentrations of uranium Žmuch below the average concentration of drinking water in Europe.. The surface soil samples showed a very large variability in uranium activity concentration, namely from 20 Bq kg 1 Ženvironmental natural uranium. to 2.3 105 Bq kg 1 Ž 18 000 mg kg 1 of depleted uranium., with concentrations above environmental levels always due to DU. The uranium isotope measurements refer to soil samples collected at places where DU ammunition had been fired; this variability indicates that the impact of DU ammunitions is very site-specific, reflecting both the physical conditions at the time of the impact of the DU ammunition and any physical and chemical alteration which occurred since then. The results on tree barks and lichens indicated the presence of DU in all cases, showing their usefulness as sensitive qualitative bio-indicators for the presence of DU dusts or aerosols formed at the time the DU ammunition had hit a hard target. This result is particularly interesting considering that at some sites, which had been hit by DU ammunition, no DU ground contamination could be detected.