Determination of organoarsenic warfare agents in sediment samples from Skagerrak by gas chromatography-mass spectrometry

In 1945 the Norwegian authorities gave permission to scuttle ships loaded with captured chemical ammunition on board in an area approximately 14 4 km in size, 25 nautical miles south-east of Arendal. An investigation was carried out in 2002 to inspect four wrecks by using a remote-operated vehicle with video cameras. The Norwegian Defence Research Establishment (Forsvarets forskningsinstitutt, FFI) carried out the project on behalf of the Norwegian Pollution Control Authority (SFT). Sediment samples were collected at eight positions around each wreck. One of the wrecks was broken up into several smaller parts. Here sediments were collected at one additional position close to one of the parts. From each position, at least two sediment cores were taken up to the surface. One of the cores from each position was sliced into three parts that were immediately frozen. The other whole cores were frozen on board the ship and transported back to the laboratory in a freezer. In total, sediment samples from 33 different locations were collected and analysed for organoarsenic warfare agents and some of their decomposition products by gas chromatography-mass spectrometry (GC-MS) after derivatisation with 1-propanethiol. Most of the identified organoarsenic compounds found in the sediment samples are parts of the arsine oil mixture produced by Germany during World War II. The compounds were found both close to the wreck and at a somewhat longer distance from the wrecks. The highest concentrations were found in a sediment sample collected close to a bomb seen on the seabed. The organoarsenic warfare agents adamsite or lewisite were not found in any of the samples. Lewisite is not reported to have been produced during World War II, but was nevertheless looked for in the samples.