Monitoring Pt and Rh in urban aerosols from Buenos Aires, Argentina

Vehicular traffic is the main source of platinum group elements (PGEs) in highly populated urban areas like Buenos Aires where a traffic density of 1,500,000 vehicles day 1 (corresponding to 7500 vehicles km 2) is estimated. Since there is no information on the levels of PGEs in Buenos Aires, a pilot study was undertaken to ascertain the amount of two major PGEs, namely Pt and Rh, in the atmosphere of this city. To this end, 49 samples of PM-10 particulate matter were collected during 7 days in seven representative sampling sites located downtown Buenos Aires and spread over an area of about 30 km2. The collection of particulate matter was performed on ash-free glass-fiber filters using high volume samplers with PM-10 sampling heads. Filters loaded with the particulate matter were subjected to microwave (MW)-assisted acid digestion using a combination of HNO3, HF and HClO4. The resulting solutions were evaporated and then diluted with 0.1 mol l 1 HCl. Analyses were performed by sector field inductively coupled plasma-mass spectrometry (SF-ICP-MS) and special attention was paid to the control of mass interferences. Statistical analysis was performed on the experimental data obtained for the element concentrations taking also into account local meteorological data for the monitored period. The highest concentrations of Pt and Rh were detected at two sites (Hospital Alema´n and Casa Rapallini) located in streets with traffic consisting mostly of passenger cars. The Pt content (in pg m 3) in airborne particulate matter was found to vary from 2.3 to 47.7, with a mean value of 12.9F7, and that of Rh from 0.3 to 16.8, with a mean value of 3.9F2.8. These concentrations are by far below the levels for which adverse health effects might be expected to occur, i.e., around 100 ng m 3. On the other hand, monitoring of PGEs should be carried out in a systematic fashion to detect possible dramatic increases from today’s levels.