Transfer of PBDEs from e-waste to aqueous media Original Research Article

Experiments and analysis were carried out by contacting e-waste with distilled water and leachate from a major urban landfill. Contacting of crushed e-waste from different eras with leachate in a custom built end-over-end contactor led to appreciable mass transfer of Polybrominated diphenyl ethers (PBDEs) to the aqueous phase. Temperature had limited influence for the limited range (10–25 °C) investigated. Lower pH (in the range 4 to 9) generally resulted in higher transfer of PBDEs to the aqueous phase. Exposing e-waste to distilled water in the same contactor led to lower, but still appreciable PBDE analysed concentrations, than for leachate, probably due to dislodgement of fine dust from the surface of the e-waste particles.