Contrasting damage characteristics in direct incidence and surface plasmon mediated single-shot laser ablation of aluminium films

Thin, oxidised Al films grown on one face of fused silica prisms are exposed, under ambient conditions, to single shots from an excimer laser operating at wavelength 248 nm. Preliminary characterisation of the films using attenuated total reflection yields optical and thickness data for the Al and Al oxide layers; this step facilitates the subsequent, accurate tuning of the excimer laser pulse to the surface plasmon resonance at the Alr oxide.rair interface and the calculation of the fluence actually absorbed by the thin film system. Ablation damage is characterised using scanning electron, and atomic force microscopy. When the laser pulse is incident, through the prism, on the sample at less than critical angle, the damage features are molten in nature with small islands of sub-micrometer dimension much in evidence; a mechanism of film melt-through and subsequent blow-off due to the build up of vapour pressure at the substraterfilm interface is appropriate. By contrast, when the optical input is surface plasmon mediated, predominately mechanical damage results with the film fragmenting into large flakes of dimensions on the order of 10 mm. It is suggested that the ability of surface plasmons to transport energy leads to enhanced, preferential absorption of energy at defect sites causing stress throughout the film which exceeds the ultimate tensile stress for the film; this in turn leads to film break-up before melting can onset. q1998 Elsevier Science B.V.