Abstract :
Pulsed laser deposition PLD.is emerging as the fastest thin film prototyping tool for a variety of multicomponent
ceramic films. There could be significant payoffs in applying this technique for the growth of GaN and related wide bandgap
semiconductor films and heterostructures primarily for their potential applications in optoelectronics and high-temperature
high-power electronics., on account of PLD’s speed and flexibility. The present work describes the pulsed laser deposition
of GaN and other participating electronic and optoelectronic materials such as AlN, TiN, and ZnO on sapphire. A pulsed
KrF excimer laser was used for ablation of the sintered stoichiometric GaN, AlN, and TiN targets. The processing
parameters such as laser fluence, substrate temperature, background gas pressure, and pulse repetition rate have been
optimized for growth of high-quality epitaxial films. The films were characterized by X-ray diffraction, Rutherford
backscattering spectrometry, ion channeling, high-resolution transmission electron microscopy, atomic force microscopy,
UV–visible spectroscopy, and electrical resistivity measurement. We also discuss pulsed laser deposition of multilayer
heterostructures of TiNrAlNrTiN as capacitors for high-temperature electronics., ZnO heteroepitaxy and its integration
with GaN for fabrication of novel devices. q1998 Elsevier Science B.V.