Title of article
Mechanism of metal cationization in organic SIMS
Author/Authors
I Wojciechowski، نويسنده , , A Delcorte، نويسنده , , X Gonze، نويسنده , , P Bertrand، نويسنده ,
Issue Information
روزنامه با شماره پیاپی سال 2003
Pages
4
From page
102
To page
105
Abstract
A scenario of metal cationization in which the organic molecule combines with a neutral excited metal atom is proposed. Ionization of the nascent complex occurs via ejection of an electron during the association process. Electron structure calculations for the model systems C6H6+Me (Me=Ag, Cu, Au) using the density functional theory give a strong argument in favor of the proposed mechanism.
Keywords
Metal cationization , Benzene , Associative ionization , Organometallics
Journal title
Applied Surface Science
Serial Year
2003
Journal title
Applied Surface Science
Record number
998398
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