Abstract :
Solid state combinatorial synthesis of oxide thin films is an attractive proposition due to the large number of compositions that
could have potentially useful properties. Thin film growth, however, presents a unique set of problems related to the formation of
heterointerfaces. Although this problem affects mostly the study of heterostructures, even simple film growth has to handle the
substrate–film interface. We have developed a technique for growing lattice constant tunable Ba1 xSrxTiO3 (BSTO)/BaTiO3
(BTO) buffer layers on SrTiO3 (STO) substrates in order to study the effects of lattice strain in a systematic way in combinatorial
thin film libraries.We show that by combining low temperature deposition and high temperature annealing, it is possible to grow
buffers with an in-plane lattice constant gradient in the range of 3.9–4.02 A ° using a composition spread Ba1 xSrxTiO3 layer.
# 2003 Elsevier B.V. All rights reserved
