عنوان به زبان ديگر :
Synthesis, Characterization, Optimization Reaction Conditions, and Molecular Weight Distribution of Poly(4-(4-nitrobenzylideneamino) phenol)
چكيده لاتين :
In this study, the conditions of oxidative polycondensation reaction of
4-(4-nitrobenzylideneamino)phenol (4-NBAP) were studied using oxidants such
as air (02), H20 2י and NaOCI in an aqueous alkaline medium of 50-90DC. Poly(4-(4-nitrobenzylideneamino)phenol) (P-4-NBAP) was characterized by 1Hand 1SC NMR, FTIR, UV-vis, size exclusion chromatography (SEC), and elemental analysis techniques. The solubility of oligomer was investigated by using organic solvents such as dimethylformamide, tetrahydrofurane, dimethylsulfoxide, methanol, ethanol, CHCls, CCI4, toluene, acetonitrile, ethyl acetate. According to air (02) oxidant (flow rate 8.5 Uh), the conversion of (4-NBAP) was 50.83% in optimum conditions such as [4-NBAPlo= [KOHlo=0.05 mol/L at 60DC for 10 h. According to the SEC analysis, the number-average molecular weight (Mn) , weight-average molecular weight (Mw) and polydispersity index (PDI) values of P-4-NBAP were found to be 11109,12886 g mol-1 and 1.160 using air (02); 17517,23402 g rnolי and 1.336 using NaOCI; and 8960, 10653 g rnolי and 1.189 using H20 2, respectively. Also, thermogravimetric analysis showed poly(4-(4-nitrobenzylideneamino)phenol) is stable against thermal decomposition. The weight loss of P-4-NBAP was found to be 49.23% at 1000DC.
