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Corresponding States Theory and Thermodynamic Properties of Liquid Alkali Metals

Mousazadeh M.H. نويسنده , Khanchi A. نويسنده , Ghanadi Marageh M. نويسنده

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According to phenomenological scaling and the law of corre sponding states, reduced coord inates Fי -T. where Fי represents the reduced thermodynamic properties (enthalpy of vaporization. speed of sound. surface tension, satur ated liquid density) and Tי is the reduced temperature. are introduced for the prediction of the thermodynamic properti es of alkali metals. Values of the thermodynamic properties from the melting point up to boiling point are correlated. It has been shown that the correlation between reduced thermodynamic properties, as well as with the reduced temperature , can be expressed as a unique straight-line plot with a linear correlation coefficient of 0.9998. The proposed correlation has a simple form for easy calcu lation, requires only the melting and boiling point parameters. which are usually easy to acquire, and can predict the thermodynamic properties from the melting temperature up to the boiling temperature accurately.

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