پديد آورندگان :
Ehsani Morteza نويسنده , Zeynali Mohammad E. نويسنده , Abtahi, Mojtaba نويسنده , Harati Abbas A. نويسنده
چكيده لاتين :
The mechanical, thermal, morphological, dynamical mechanical and electrical
properties of polymeric insulators are tested and reported. Low density polyethylene
(LDPE), ethylene-propylene-diene monomer (EPDM) and blends of
LDPE/EPDM are known polymers for use as low, medium and high voltage insulators.
Several formulations containing EPDM and LDPE were prepared. EPDM was blended
with LDPE in different weight ratios of LDPE/EPDM (100/0, 80/20, 60/40, 50/50, 40/60,
20/80, 0/100). The change in Haake-viscosity mixing torque with time for different blend
compositions was obtained. The torque at any time is dependent on the blend composition.
For EPDM the observed torque is directly influenced by its cross-linking density.
However, for LDPE or blends of high percentage of LDPE the influence of cross-linking
density on torque is relatively low. The mechanical properties of cross-linked EPDM are
weaker than LDPE. Therefore changing the cross-link density of EPDM will not affect
the blend properties significantly especially at high LDPE content. A drop shape analysis
system G l0 (Kruss-USA) was used for hydrophobicity studies. Studies illustrate that
in LDPE/EPDM blends, tensile strength of the blends are higher than either polymer
component alone. But the synergism effect in LDPE/EPDM compound is stronger than
HDPE/EPDM. Also the blends of LDPE/EPDM show good breakdown voltage strength
and heat resistance comparing to LDPE. The result of mechanical measurement shows
that mechanical properties such as tensile strength, modulus and elongation-at-break
of blends can be enhanced with increase in LDPE in the formulation. Also tests were
conducted to study various properties (mechanical, surface, electrical) under accelerated
ageing condition. Because the life time of these compounds are generally too long
to wait for a verdict on their behaviour in use. The ageing results show that mechanical
properties follow the same trend as pre-ageing stage.