شماره ركورد :
18999
عنوان به زبان ديگر :
The Investigation of Equilibria in Solution
پديد آورندگان :
Maedera M. نويسنده , Abdollahi H. نويسنده
از صفحه :
522
تا صفحه :
534
تعداد صفحه :
13
چكيده لاتين :
This contribution describes the practical and computational aspects relevant for the quantitative analysis of chemical equilibria. First a systematic nomenclature based on stability constants is introduced. Next, practical aspects of potentiometric pH titrations and spectrophotometric titrations are discussed. The description of the computational aspects includes the Newton- Raphson algorithm that allows the computation of all species concentrations for a given model, set of formation constants and total component concentrations. The second computational part introduces the Newton-Gauss algorithm for non-linear data fitting. Three practical examples illustrate all the above. They include the spectrophotometric investigations of the interaction of Bi(III) with Cl-, of Cu(II) with EDTA and the potentiometric investigation of the Zn(II) ethylenediamine system. All Matlab softwares for the data generation and analysis are available from the authors.
شماره مدرك :
1202983
لينک به اين مدرک :
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