چكيده لاتين :
Polymer supported reagents have become the subject of considerable and
increasing interest as insoluble materials in the organic synthesis. The attachment
of the reagents to the insoluble macromolecular matrix can solve the problems
of tedious work-up, lability, toxicity, or unrecyclability often experienced with nonpolymeric
low-molecular weight reagents. A literature survey shows that a review on
poly(vinylpyridine)-supported reagents is not available yet. This review will focus on
the implementation of methodologies for polymer supported reagents based on
poly(vinylpyridine) (PVPy), in the organic synthesis appeared in the literature until the
year of 2009. The aim is to distill the literature into three categories and to present
each as a short table listing the functionalized polymers involved, along with their
relevant applications as reagents. In the text, discussions on the structural and transformation
of some typical polymeric reagents are given, although there is not detailed
procedure provided in the text about the synthesis of the polymers or their transformations.
When appropriate, comparison between the behaviour of supported reagents
versus non-supported reagents is attempted. This review does not include the patent
literature.
