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An Efficient Catalyst-Free Ring Opening of Epoxides in PEG-300: A Versatile Method for the Synthesis of Vicinal Azidoalcohols

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Efficient and regioselective conversion of epoxides to 1,2-azidoalcohols has been carried out by treatment of sodium azide using polyethylene glycol as the reaction medium. The reaction afforded the corresponding products with high regioselectivity under mild reaction conditions.

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