عنوان مقاله :
Synthesis and Characterization of New Copper (II) Complexes with mixed ligand of Heterocyclic Dithiocarbamates and 4-picoline,luitidine ,en,(1- 10)phen,pph_3
پديد آورندگان :
mohammed, hasan a. university of kirkuk - college of science - department of chemistry, Iraq , mukhtar, saad e. al. university of mosul - college of science - department of chemistry, iraq
چكيده فارسي :
New copper (II) complexes containing mixed ligands of the general formula [Cu(4- Hydrpipdtc)_2L_2] and [Cu(4-methylpipdtc)_2L_2], where (4-Hydrpipdtc), (4-methylpipdtc)=4-hydroxylpiperidinedithiocarbamate , 4-methylpiperidinedithiocarbamate respectively and L= 4-picoline ,luitidine ,en ,(1-10)phen,PPh_3 , have been prepared and characterized by elemental analyses ,conductivity , infrared ,electronic spectra and susceptibility measurements . From the obtained data a square planar geometry was suggested for the bis (dithiocarbamato) copper (II) complex and octahedral geometry for the others has been suggested.
كليدواژه :
Heterocyclic , Dithiocarbamates , Copper (II) , Complexes , mixed ligand
عنوان نشريه :
Kirkuk University Journal: Scientific Studies