شماره ركورد كنفرانس :
580
عنوان مقاله :
KINETICS OF REACTION BETWEEN DMAD AND MELDRUM’S ACID IN THE PRESENCE OF TRIPHENYLARSINE
عنوان به زبان ديگر :
KINETICS OF REACTION BETWEEN DMAD AND MELDRUM’S ACID IN THE PRESENCE OF TRIPHENYLARSINE
پديدآورندگان :
Ghodsi F نويسنده , Habibi-Khorassani S.M نويسنده , Shahraki M نويسنده , Hashemi-Shahri M نويسنده
كليدواژه :
dimethyl acetylendicarboxcylate , Meldrum’s acid , Mechanism , UV spectroscopy , Kinetics
عنوان كنفرانس :
سومين همايش تكنتيك هاي نوين در شيمي و پتروشيمي نانو ايران
چكيده لاتين :
The kinetics and mechanistic investigation of the reaction between dimethyl acetylendicarboxcylate (DMAD) and Meldrum’s acid has been studied in ethanol environment with triphenylarsine as a catalyst using UV/vis spectrophotometry. The reaction followed second order kinetics. In the kinetics study, activation energy and parameters (Ea, ΔHǂ, ΔSǂ and ΔGǂ) were determined. Also, reaction rate is accelerated by increasing the temperature and the dielectric constant of solvent
شماره مدرك كنفرانس :
4456290
