شماره ركورد كنفرانس :
3776
عنوان مقاله :
Synthesis of Amino Silane derivatives by reaction of imines in the presenceof lithium
پديدآورندگان :
Entezari Elahe Elahe.entezari70@gmail.com AzarbaijanshahidMadani University , Galehassadi Mohammad AzarbaijanshahidMadani University
تعداد صفحه :
1
كليدواژه :
,
سال انتشار :
1395
عنوان كنفرانس :
بيست چهارمين سمينار شيمي آلي ايران
زبان مدرك :
انگليسي
چكيده فارسي :
Silylmethylamines are defined as compounds in which one silicon and one nitrogen atom are directly linked to a sp3-carbon atom [1]. Many silylamine derivatives prepared by the reaction of imines and silylation reagents such as trimethylchlorosilane [2]. This compounds have many bilogical activity specialy antioxidant, anticancer, antibacterial and anti-tumor activity [1]. Silylamine reversible ionic liquids were designed to achieve specific physical properties in order to address effective CO2 capture. The current-and the only implemented-technology that enables the capture of CO2 is the use of aqueous amine solutions. In particular, 30% monoethanolamin (MEA) in water is most often used because MEA exhibits high CO2 capacity and high reactivity (chemisorption). Silylamines (molecular liquids) reversibly react with CO2 to form ammonium carbamates (reversible ionic liquids). Two moles of molecular liquid react with one mole of CO2 ]3[, this properties prompted us to synthesize the new derivatives of them. In this work a new α-silylamine derivative was prepared by the reaction of imine 1 with the trimethylsilylchloride in the present of lithium in THF (Scheme 1). The product was extracted from reaction mixture by distillation. The structure of this compound was charactrized from FT-IR and 1HNMR sppctra.
كشور :
ايران
لينک به اين مدرک :
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