شماره ركورد كنفرانس :
3834
عنوان مقاله :
RATIONAL DESIGN, SYNTHESIS AND CO2 SORPTION PROPERTIES OF
AMIDE FUNCTIONALIZED METAL-ORGANIC FRAMEWORKS
پديدآورندگان :
Safarifard Vahid vahidsafarifard@gmail.com Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, Iran; , Bigdeli Mina Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, Iran , Morsali Ali Department of Chemistry, Faculty of Sciences, Tarbiat Modares University, Tehran, Iran
كليدواژه :
Metal , Organic Frameworks , CO2 sorption , Microporous
عنوان كنفرانس :
نوزدهمين سمينار شيمي فيزيك ايران
چكيده فارسي :
We report here the use of a pillaring strategy for the design and synthesis of a novel –amide functionalized- metal-organic framework (MOF), TMU-24, isoreticular to the recently reported –imine containing TMU-21 MOF. CO2 sorption measurement revealed a better efficiency of amide functionalization compared to imines. Indeed, at 195 K, the amide functionalized material saturate at much lower pressure than the parent, imine containing analog.
