شماره ركورد كنفرانس :
4014
عنوان مقاله :
Electrochemical oxidation of polybutadiene/organoclay nanocomposite by silver (II)
پديدآورندگان :
Ronagh-Baghban Mohammad F.Mohammadi@ippi.ac.ir Iran Polymer and Petrochemical Institute , Mohammadi Fereidoon F.Mohammadi@ippi.ac.ir Iran Polymer and Petrochemical Institute , Naderi Ghasem F.Mohammadi@ippi.ac.ir Iran Polymer and Petrochemical Institute
كليدواژه :
Polybutadiene , Organoclay nanocomposite , Silver(II) , Mediated electrochemical oxidation , Characterization.
عنوان كنفرانس :
دوازدهمين سمينار سالانه الكتروشيمي ايران
چكيده فارسي :
Electrochemically generated Silver (II) was used for mediated electrochemical oxidation (MEO)
of vulcanized polybutadiene/organoclay nanocomposite (BRN). X-ray diffraction (XRD) pattern
and transmission electron microscopy (TEM) pictures verified intercalated organoclay/Cloisite
20A morphology in the BRN matrix. Atomic force microscopy (AFM) revealed that surface
roughness of BRN samples were considerably enhanced after oxidation. Scanning electron
microscopy (SEM) micrographs showed that weak boundary layer (WBL) on the rubber surface
was clearly removed after 600 seconds, further oxidation led to surface degradation due to
creation of holes and cracks.
