شماره ركورد كنفرانس :
4865
عنوان مقاله :
Long-Term Activity of Pd-Co/rGO Nano-Catalyst in Ethylene Glycol Electro-oxidation Reaction in Alkaline Media
پديدآورندگان :
Majidia Somayeh somaye.majidi2010@gmail.com , Islamic Azad University, Najafabad , Asgarib Hamidreza rezah7554@gmail.com , Islamic Azad University, Najafabad
كليدواژه :
Pd , Co , rGO , Ethylene glycol , Electro , oxidation , Long , term activity , Alkaline media.
عنوان كنفرانس :
بيست و دومين كنفرانس ملي شيمي فيزيك ايران
چكيده فارسي :
The Pd-Co/rGO nano-catalysts were used as electro-catalysts for the ethylene glycol (EG) oxidation reaction in alkaline media. The long-term activity of Pd-Co/rGO was investigated in the Half-cell by electrochemical techniques such as cyclic voltammetry (CV) and chronoamperometry (CA) techniques. CV results of EG electro-oxidation reaction on the Pd-Co/rGO were compared to the reported results in the literature. Eonset and Sap were -0.3 V and 450 (mA/ mgPd) , respectively, suggesting an excellent activity of Pd-Co/rGO in EG oxidation reaction in alkaline media. The low long term poisoning rate (0.018) of Pd-Co/rGO resulted from CA test determines high long-term activity and stability of Pd-Co/rGO in EG electro-oxidation reaction.