شماره ركورد كنفرانس :
4887
عنوان مقاله :
Preparation of CNTs / Polyrhodanine nanocomposites through one - step chemical oxidation polymerization
پديدآورندگان :
Alizadeh Bahareh M.Sc.Student of Chemical Engineering The University of Giulan ,Rasht ,Iran , Salehi Mohammad Ali Department of Chemical Engineering The University of Giulan ,Rasht ,Iran , Ghorbani Mohsen Faculty of Chemical Engineering,Babol Noshirvani University of Technology, Babol, Iran
كليدواژه :
Polyrhodanine , Synthesize , Nanocomposite , CNTs , Characterization
عنوان كنفرانس :
پانزدهمين كنگره ملي مهندسي شيمي ايران
چكيده فارسي :
Rhodanine is a less-known conductive polymer, which due to owing strong metal binding sites (nitrogen, sulfur and oxygen) in its monomeric unit, has potential application in various field. In this research CNTs/Polyrhodanine nanocomposites were synthesized by chemical oxidative polymerization of rhodanine monomer at the carbon nano tubes surface, in presence of Potassium permanganate (kmno4) as an oxidant and Poly (Vinyle Plorridone) (PVP) as surfactant. characterization of CNTs / Poly rhodanine nanocomposites were conducted using the fourier transform infrared spectroscopy (FTIR), which is confirmed that the chemical oxidation polymerization of CNTs/Poly rhodanine was successfully performed and polymer chain formed on surface of CNTs. which is later indicated clearly by scaning electronic microscope ( SEM ) in which pictures show that smooth surface of CNTs (diameter: 10–20 nm) turns into rough structure and its diameter increases to around 60 nm ,which can attributed to the Poly rhodanine on CNT surfacese