شماره ركورد كنفرانس :
5115
عنوان مقاله :
Improving stability of UiO-66 with external modification
پديدآورندگان :
Hoseini Hajar Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran , Bastani Dariush bastani@sharif.edu Department of Chemical and Petroleum Engineering, Sharif University of Technology, Tehran, Iran , Mousavi Abbas musavi@sharif.edu Department of Chemical and Petroleum Engineering,Sharif University of Technology, Tehran, Iran
كليدواژه :
MOF modification# hydrophobic MOF#
عنوان كنفرانس :
هفدهمين كنگره ملي مهندسي شيمي ايران
چكيده فارسي :
In this work, we demonstrate a facile method that imparts hydrophobic character to UiO-66 , while retaining their porosity. The long alkyl chain of stearic acid with low surface energy was grafted onto the surface of UiO-66, which would make UiO-66 high water resistance, yielding a hydrophobic material with a contact angle of 93°. The products were characterized by BET, XRD methods to monitor their textural properties before and after functionalization. The results indicated that stearic acid was successfully grafted to the UiO-66 framework. Therefore, we were able to greatly improve the stability of UiO-66.
