پديدآورندگان :
Vafakish Elmira Polymer Engineeringgroup, Chemical Engineering Department, TarbiatModares University, Tehran, I. R. Iran , Razzaghi-Kashani Mehdi mehdi.razzaghi@modares.ac.ir Polymer Engineeringgroup, Chemical Engineering Department, TarbiatModares University, Tehran, I. R. Iran , Hosseini Seyed Mostaffa Polymer Engineeringgroup, Chemical Engineering Department, TarbiatModares University, Tehran, I. R. Iran
كليدواژه :
Elastomer , Solution , polymerized styrene , butadiene rubber , Nano silica , Vulcanization kinetics.
چكيده فارسي :
It was shown that the physical filler-polymer and filler-filler interactions has a substantial role in controlling the vulcanization kinetics of solution-polymerized styrene-butadiene rubber (SSBR)/butadiene rubber filled with nano-silica in a sulfur vulcanization system. Kinetic studies by the oscillating disc rheometer revealed that the vulcanization rate suppressed as vinyl molecular microstructure of SSBR increases. A mechanism was proposed which correlates vulcanization kinetics of compounds to the dynamics of chains influenced by the SSBR molecular microstructure.
