شماره ركورد كنفرانس :
5536
عنوان مقاله :
Control of hydrogen response for Polypropylene Obtained by Ziegler-Natta Catalyst: Effect of External Donor
پديدآورندگان :
Ghasemi Hamedani Nona National Petrochemical Company- Research Technology Co. (NPC-RT), Tehran, Iran , Kohestanian mohammad National Petrochemical Company- Research Technology Co. (NPC-RT), Tehran, Iran , poorsank Fatemeh f.poorsank@ippi.ac.ir National Petrochemical Company- Research Technology Co. (NPC-RT), Tehran, Iran
كليدواژه :
Ziegler Natta catalyst , External donor , Polypropylene
عنوان كنفرانس :
پانزدهمين همايش بين المللي علوم و فناوري پليمر
چكيده فارسي :
An insight into the effect of different external donor structures, comprised of diisopropyl dimethoxy propane (DMP) and 2,2-diisopropyl succinate (IPS), bis benzyloxy dimethy silan (BDS) on the performance of MgCl2 supported Ziegler-Natta catalyst in propylene polymerization is developed and the resules compared with conventional alkoxysilane (C) external donor. Using DMP as external donor showed higher activity than IPS and BDS. On the other hand, DMP as external donor is more efficient in converting low molar mass centers to higher ones. Meanwhile, It showes higher hydrogen response in comparison to alkoxysilane (C). A promising feature of these data is providing a guideline to study the effect of diether and succinate compounds as external donor.
