Author/Authors :
Özöğüt, Devrim Eskişehir Osmangazi Üniversitesi - Fen Edebiyat Fakültesi - Kimya Bölümü, Turkey , Bilgiç, Sevim Eskişehir Osmangazi Üniversitesi - Fen Edebiyat Fakültesi - Kimya Bölümü, Turkey , Açıkkalp, Erol Eskişehir Osmangazi Üniversitesi - Fen Edebiyat Fakültesi - Kimya Bölümü, Turkey
Title Of Article :
The Synthesis and Determination of Structure of 1-{[( 2-Iodo-4-Nitrophenyl) Imino] Methyl}2-Naphthol
Abstract :
In this paper, naphtholic Schiff base 1-{[(4-nitrofenil) imino] metil}2-naftol (1), which was prepared of reaction 2-hydroxy-1-naphtaldehyde and 4-NO2 aniline were reacted with DMSO, I2, H2SO4 in the hope of preparing naphtholic Schiff base which was subtituted with iodine. Thin-layer chromatography was used as a method of separation and purification. Forming product (2) was purified with preperative TLC (SiO2/C6H6) (Rf=0.64). The structure of product was determined by IR, UV, 1H-NMR and mass spectra. Under our reaction condition iodine was substituted to the phenyl ring of the 4-NO2 naphtholic Schiff base (1). Iodine substitue naphtholic Schiff base (2) has formulation to 1-{[(2-iodo-4-nitrophenyl) imino] methyl}2-naphthol and it is original.
NaturalLanguageKeyword :
Schiff base , Aromatic iodination , chromatography , spectrum
JournalTitle :
Afyon Kocatepe University Journal Of Science and Engineering
