tribak, z. sidi mohamed ben abdellah university - faculty of science and technology - laboratory of applied chemistry, Morocco , kandri rodi, y. université sidi mohamed ben abdallah - faculty of science and technology - laboratory of applied organic chemistry, Morocco , haoudi, a. université sidi mohamed ben abdallah - faculty of science and technology - laboratory of applied chemistry, Morocco , skalli, m.k. sidi mohamed ben abdellah university - faculty of science and technology - laboratory of applied chemistry, Morocco , mazzah, a. université lille1 - science and technology of lille, usr 3290, France , ouzidan, y. sidi mohamed ben abdellah university - faculty of science and technology - laboratory of applied organic chemistry, Morocco , senhaji, o. , moulay ismaïl university - faculty of sciences and technology of errachidia - laboratory of applied physical chemistry, Morocco , essassi, e.m. mohammed vuniversity - faculty of sciences - laboratory of organic heterocyclic chemistry urac 21, Morocco

THEORETICAL AND EXPERIMENTAL STUDY OF THE REGIOSECTIVITY OF THE NEW 1,2,3-TRIAZOLES DERIVED FROM 5-CHLOROISATIN

28010

In this work, we theoretical study 1,3-Dipolar Cycloaddition between benzylazide and 5-chloro-1-(prop-2-yn-1-yl)indoline-2,3-dione. Based on the DFT calculation method with the standard basis set 6-31G and the functional base B3LYP, we discuss, from experimental regiochemistry and orbital points of view, the possibility and the stereoselectivity of this reaction. The theoretical results are consistent with experience.

110

5 , chloro , 1 , (prop , 2 , yn , 1 , yl) indoline , 2 , 3 , dione , dipolarophile , 1 , 3 , Dipolar Cycloaddition , theoretical study , DFT

Journal Marocain De Chimie Hétérocyclique

118