Author/Authors :
sağlam, meltem betül karadeniz technical university - faculty of sciences - department of chemistry, Turkey
Title Of Article :
MICROWAVE-ASSISTED SYNTHESIS AND CHARACTERIZATION OF A NEW METALFREE PHTHALOCYANINE AND FOUR METALLOPHTHALOCYANINES BEARING 9- FLOURENE METHANOL MOITIES
Abstract :
The new metal-free phthalocyanine 2 and metallophtalocyanines 3, 4, 5, 6 containing 9-flourene methanol units on peripheral positions have been synthesized by cyclotetramerization reaction of a corresponding nitrile compound. The metal-free phthalocyanine 2 was synthesized in dry n-pentanol by a classical method. Hovewer, metal phthalocyanines complexes 3, 4, 5, 6, were synthesized by the reaction of dinitrile derivative 2 in DMAE, by microwave irradiation. The structure of the new compounds were characterized by using spectroscopic data and elemental analysis.
NaturalLanguageKeyword :
Nitrile , Metallophthalocyanine , Cyclotetramerization , Macrocyclic
JournalTitle :
Anadolu University Journal of Science and Technology. A : Applied Sciences and Engineering
