We report the preliminary results of a program recently begun at Argonne National Laboratory to demonstrate the feasibility of using niobium nitride (NbN) films as practical high field superconductors. Films of varying thicknesses (2-9 μm) have been deposited on sapphire and Hastelloy substrates, using d.c. magnetron sputtering. The superconducting transition temperatures T
cof these films range from 12-15 K. Using the WHH extrapolation, upper critical fields H
c2(O) up to 36 T in the parallel direction and 43T in the perpendicular direction were obtained. Critical current densities J
c(H,4.2 K) were

A/cm
2at 20 T in both the parallel and perpendicular directions. The preliminary results from novel sample preparation technique for TEM studies of film cross-sections is briefly described. This technique shows the variation in film structure as a function of distance from the substrate.