Expressions are derived for the probability

that a pulse initiated by

electrons (or holes) in a uniformly multiplying semiconductor diode will result in a total number of electrons (or holes)

, to give a gain

, and for the probability

that the gain will be

or greater. It is shown that the distributions are far from Gaussian. The gain distribution

for a single photoelectron, for example, is shown to have a maximum value for

for any value of the average gain

. The derivations are valid for any electric field distribution and assume only that the hole ionization coefficient

) can be approximated by the relation

, where

is the electron ionization coefficient and

is a constant. A method of determining an effective value of

, for cases where

is not a good approximation, is presented. The results can be used to calculate the average gain and the mean square deviation from the average, giving results in agreement with previously published relations [1], [2]. The implications of this theory on the use of avalanche diodes for low-level photodetection are discussed. It is shown that in the near infrared, cooled avalanche photodiodes can compare favorably with the best available photomultiplier when used either in a photon-counting mode, or for the reliable detection of low-level laser pulses.