SiC/Si heterojunction diodes fabricated by self-selective and by blanket rapid thermal chemical vapor deposition

SiC/Si heterojunction diodes have been fabricated by two different rapid thermal chemical vapor deposition (RTCVD) processes: a localized self-selective growth and blanket growth. The self-selective growth of crystalline cubic (β) SiC was obtained by propane carbonization of the Si substrate in regions unprotected by an SiO₂ layer, producing planar diodes. Mesa diodes were fabricated using the blanket growth of polycrystalline β-SiC produced by the decomposition of methylsilane (CH₃SiH₃). The SiC/Si heterojunction diodes show good rectifying properties for both device structures. Reverse breakdown voltage of 50 V was obtained with the self-selective SiC/Si diode. The mesa diodes exhibited even higher breakdown voltages (V_br) of 150 V and excellent ideality factors of 1.06 at 25°C. The high V_br and good forward rectifying characteristics indicate that the SiC/Si heterojunction diode represents a promising approach for the fabrication of wide-gap emitter SiC/Si heterojunction bipolar transistors