Nanofilled silicone dielectrics prepared with surfactant for outdoor insulation applications

This paper reports on the heat erosion resistance of various silicone rubber compositions under infrared laser heating that simulates the dry band arcing phenomenon on outdoor insulation. The composites are made using a two-part addition cure silicone rubber, with various amounts of alumina, natural silica, or fumed silica, nano-or micron size, and different amounts of Tritontrade X-100 surfactant. It is shown that the surfactant greatly improves the dispersion of nanosized particles, yielding composites that are more homogeneous, with improved resistance to heat ablation. Significantly improved dispersion in the presence of surfactant is confirmed by SEM analysis for some nanofillers, while very little effect is observed for others. The surfactant is beneficial up to the point where the filler surface is saturated with the additive. Fumed silica is shown to impart greater heat ablation resistance than natural silica and alumina. Furthermore, a distinct protection mechanism appears to be operative for fumed silica and natural silica as opposed to alumina.