The photoionization cross section of excited atomic selenium, Se(
1S
0), obtained by photodissociation of OCSe, has been measured in the wavelength region of 170-175 nm using a tunable xenon laser. A minimum value, at 172 nm, was found to be

cm
2, approximately ten times less than a recently calculated value. The photodissociation cross section for OCSe, at the same wavelength, was found to be

cm
2, in good agreement with published work. The effect of an election cooling buffer gas upon the electron production from excited selenium was also investigated.