The liquid-phase epitaxy and device fabrication of p-n and p-i-n Ga
1-xAl
xSb avalanche photodiodes is described. Breakdown voltages up to 95 V and dark currents of 10
-4A/cm
2have been obtained. With p-i-n diodes we have measured the impact ionization coefficients α (electrons) and β (holes) with different composition and temperature. A resonant enhancement of the hole ionization coefficient is found for

(300 K) where the ratio

exceeds values of 20. This effect is attributed to impact ionization initiated by holes from the split-off valence band: if the spin orbit splitting Δ is equal to the bandgap energy E
g, the threshold energy for hole initiated impact ionization reaches the smallest possible value (

) and the ionization process occurs with zero momentum. This leads to a strong increase of β at

. The experimentally determined dependence of ionization coefficients on threshold energy is compared with theoretical expectations.