The temperature of electrons confined in a single quantum well (SQW) as a function of well width (L
z) from

Å to

Å have been determined from photoluminescence spectra of a set of undoped (Al,In)As/(Ga,In)As SQW\´s. From steady state electron temperature variation with L
zit is shown that the electron and longitudinal optical phonon scattering dominates the excess energy loss of the thermalized two dimensional electrons in the SQW\´s and the scattering rate is independent of L
zwithin our experimental accuracy. The average energy loss rate per hot-electron was determined to be much smaller than expected.