Title :
High Density Polyethylene (HDPE) Clay Nanocomposite for Dielectric Applications
Author :
Shah, K.S. ; Jain, R.C. ; Shrinet, V. ; Singh, A.K. ; Bharambe, D.P.
Author_Institution :
Mater. Res. Cell, Electr. Res. & Dev. Assoc., Vadodara
fDate :
6/1/2009 12:00:00 AM
Abstract :
Indigenous Montmorillonite clay available from Kutchh region in western part of India was modified by Hexadecyl trimethyl ammonium bromide, a quaternary ammonium compound to make it organophilic. It was blended with high density polyethylene (HDPE) in a Brabender Plasticoder. The condition for blending was optimized and sheets were prepared for evaluating mechanical, electrical and thermal properties. Mechanical property such as tensile was improved. The electrical properties such as dielectric strength, volume resistivity and surface resistivity were measured as per ASTM D149 and ASTM D257 standards. It was observed that electrical properties of nanoclay composite improved significantly when organoclay was treated with silane and titanate compounds. Thermal characterization of the HDPE and HDPE clay nanocomposite had been carried out by thermogravimetric analysis (TGA). It has been observed that the thermal stability of the nanocomposite increases significantly when the silane and titanate coupling agents are used.
Keywords :
clay; electric strength; electrical resistivity; filled polymers; nanocomposites; nanotechnology; sheet materials; surface resistance; tensile strength; thermal analysis; thermal stability; ASTM D149 standards; ASTM D257 standards; HDPE; TGA; dielectric strength; electrical properties; hexadecyl trimethyl ammonium bromide; high density polyethylene clay; indigenous montmorillonite clay; mechanical properties; nanoclay composite; nanocomposite materials; organophilic compound; quaternary ammonium compound; sheet materials; silane compounds; surface resistivity; tensile strength; thermal properties; thermal stability; thermogravimetric analysis; titanate coupling agents; Conductivity; Dielectric breakdown; Dielectric measurements; Electric variables measurement; Measurement standards; Mechanical factors; Polyethylene; Surface treatment; Titanium compounds; Volume measurement; Dielectric, nanocomposite, silane coupling agent, titanate coupling agent, montmorillonite clay, quaternary ammonium compound;
Journal_Title :
Dielectrics and Electrical Insulation, IEEE Transactions on
DOI :
10.1109/TDEI.2009.5128526