• DocumentCode
    1116228
  • Title

    Absorption loss due to complex anions in fluorozirconate glasses

  • Author

    Poulain, Marcel ; Saad, Mohammed

  • Author_Institution
    Université de Rennes, Rennes Cedex, France
  • Volume
    2
  • Issue
    5
  • fYear
    1984
  • fDate
    10/1/1984 12:00:00 AM
  • Firstpage
    599
  • Lastpage
    602
  • Abstract
    A fluorozirconate glass ZBL-3 with the molar composition 0.62 ZrF4, 0.33 BaF2, 0.05 LaF3was doped with various amounts of NaPO3, KHSO4, and also with Na2CO3, NaNO3and TiOF2. Characteristic absorption bands were observed at 2100 cm-1and 1640 cm-1for phosphates and 2150, 2350, and 1600 cm-1for sulfates. The absorption resulting from 1 ppm of P is 900 dB/km at 2100 cm-1while it is slightly lower for 1 ppm of S. Carbonates and nitrates are decomposed in the glass melt and result in a small shift of the infrared multiphonon absorption.
  • Keywords
    Optical fiber materials/fabrication; Atom optics; Electromagnetic wave absorption; Glass manufacturing; Infrared spectra; Optical refraction; Optical variables control; Phonons; Propagation losses; Refractive index;
  • fLanguage
    English
  • Journal_Title
    Lightwave Technology, Journal of
  • Publisher
    ieee
  • ISSN
    0733-8724
  • Type

    jour

  • DOI
    10.1109/JLT.1984.1073662
  • Filename
    1073662