DocumentCode
1116228
Title
Absorption loss due to complex anions in fluorozirconate glasses
Author
Poulain, Marcel ; Saad, Mohammed
Author_Institution
Université de Rennes, Rennes Cedex, France
Volume
2
Issue
5
fYear
1984
fDate
10/1/1984 12:00:00 AM
Firstpage
599
Lastpage
602
Abstract
A fluorozirconate glass ZBL-3 with the molar composition 0.62 ZrF4 , 0.33 BaF2 , 0.05 LaF3 was doped with various amounts of NaPO3 , KHSO4 , and also with Na2 CO3 , NaNO3 and TiOF2 . Characteristic absorption bands were observed at 2100 cm-1and 1640 cm-1for phosphates and 2150, 2350, and 1600 cm-1for sulfates. The absorption resulting from 1 ppm of P is 900 dB/km at 2100 cm-1while it is slightly lower for 1 ppm of S. Carbonates and nitrates are decomposed in the glass melt and result in a small shift of the infrared multiphonon absorption.
Keywords
Optical fiber materials/fabrication; Atom optics; Electromagnetic wave absorption; Glass manufacturing; Infrared spectra; Optical refraction; Optical variables control; Phonons; Propagation losses; Refractive index;
fLanguage
English
Journal_Title
Lightwave Technology, Journal of
Publisher
ieee
ISSN
0733-8724
Type
jour
DOI
10.1109/JLT.1984.1073662
Filename
1073662
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