Using departure from stoichiometry, p-n junctions were prepared in Cd
xHg
1-xTe with

for the study of photovoltaic detection at 10.6 μ. In the final photodiodes, with sensitive areas between

and 10
-3cm
2, values such as

and 8 pF have been observed at -0.1 V reverse bias for the shunt resistance and capacitance at 77°K. The CO
2laser detection characteristics were investigated, leading to 10
10< D
*(10.6 μ, 1800 Hz, 1 Hz)

cm W
-1Hz
1/2, a frequency response flat up to 1 GHz, a heterodyne noise equivalent power (NEP) =

W/Hz with l-mW local oscillator power. Studies as a function of the temperature indicated that substantial sensitivity can be obtained up to 135°K.