Title :
Mossbauer study of amorphous (FeTM)80B20
Author :
Orue, I. ; Plazaola, F. ; Fernandez-Gubieda, Maria Luisa ; Gutierrez, Jessica ; Barandiaran, Jose Manuel
Author_Institution :
Dept. de Electr. y Electron., Pais Vasco Univ., Bilbao, Spain
fDate :
3/1/1994 12:00:00 AM
Abstract :
“As-cast” ferromagnetic amorphous alloys of nominal composition (FeTM)80B20 have been studied by Mossbauer spectroscopy, being TM one transition metal atom, Ni, Cr, Mo or Pd. A detailed analysis of the isomer shift, IS, and hyperfine field distribution, HFD, at Fe sites is reported in order to achieve some conclusions about the chemical short range order and the electronic structure in these alloys. HFD changes found in (FeNi)B for Ni rich concentrations suggest the existence of Fe atoms strongly interacting with Ni. Small amounts of Cr and Mo shift the HFD to lower values of hyperfine field, Bhf, while Pd enhances the Bhf
Keywords :
Mossbauer effect; boron alloys; electron energy states of amorphous solids; ferromagnetic properties of substances; hyperfine field interactions (condensed matter); iron alloys; isomer shift; magnetic properties of amorphous substances; metallic glasses; short-range order; transition metal alloys; (FeCr)80B20; (FeMo)80B20; (FeNi)80B20; (FePd)80B20; Mossbauer study; amorphous (FeTM)80B20; chemical short range order; electronic structure; ferromagnetic; hyperfine field distribution; isomer shift; Amorphous magnetic materials; Amorphous materials; Chemical analysis; Chromium alloys; Germanium alloys; Iron alloys; Magnetic resonance; Nickel alloys; Silicon alloys; Spectroscopy;
Journal_Title :
Magnetics, IEEE Transactions on