DocumentCode :
1196183
Title :
Transition Metal Exchanged Zeolite Layers for Selectivity Enhancement of Metal-Oxide Semiconductor Gas Sensors
Author :
Mann, Dominic P. ; Pratt, Keith F E ; Paraskeva, Themis ; Parkin, Ivan P. ; Williams, David E.
Author_Institution :
Aeroqual Ltd, Auckland
Volume :
7
Issue :
4
fYear :
2007
fDate :
4/1/2007 12:00:00 AM
Firstpage :
551
Lastpage :
556
Abstract :
A novel method of improving the selectivity of metal oxide gas sensors has been developed by using catalytically active molecular sieve materials. They have been successfully introduced into a proprietary sensor array. The cracking patterns of linear alkanes over transition metal exchanged zeolite Y have been measured using a zeolite bed/GC/MS experimental set-up within a temperature range of 300degC to 400degC. Studies have been carried out regarding the effects of metal loading, zeolite type, material fabrication techniques, and operating temperature in relation to catalytic activity and selectivity. The composite sensors utilising the novel zeolite materials have been used in a custom built sensor rig that houses three dual electrode sensors and can measure real-time responses of these sensors to an introduced headspace generated from organic liquids
Keywords :
MIS devices; catalysis; electrodes; gas sensors; molecular sieves; organic compounds; transition metals; zeolites; 300 to 400 C; catalytic activity; catalytically active molecular sieve materials; cracking patterns; dual electrode sensors; linear alkanes; material fabrication techniques; metal loading; metal-oxide semiconductor gas sensors; organic liquids; transition metal exchanged zeolite layers; zeolite bed/GC/MS experimental set-up; zeolite materials; zeolite type; Composite materials; Fabrication; Gas detectors; Inorganic materials; MOS devices; Molecular sieves; Semiconductor materials; Sensor arrays; Temperature distribution; Temperature sensors; Alkanes; gas sensor; selectivity; zeolite;
fLanguage :
English
Journal_Title :
Sensors Journal, IEEE
Publisher :
ieee
ISSN :
1530-437X
Type :
jour
DOI :
10.1109/JSEN.2007.891956
Filename :
4118158
Link To Document :
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