• DocumentCode
    1206071
  • Title

    Co3O34 mono-dispersed nanoparticle solubility in high-purity water

  • Author

    Lihong, S. ; Yiguang, W. ; Shengru, Q. ; Jiaoqiang, Z. ; Xu, Zongben ; Lingjun, G. ; Lihua, S. ; Yujie, S. ; Yanling, A. ; Qin, Chunbin

  • Author_Institution
    Northwestern Polytech. Univ., Xi´an
  • Volume
    4
  • Issue
    1
  • fYear
    2009
  • fDate
    3/1/2009 12:00:00 AM
  • Firstpage
    48
  • Lastpage
    52
  • Abstract
    As more and more nanoparticles are synthesised and applied in industry and society, their safety has started to become an environmental concern. The solubility of Co3O4 particles with different morphology and sizes were investigated. The solubility of the mono-dispersed Co3O4 nanoparticle was discovered to be much lower than that of its micrometre counter-partners. A mechanism was proposed to interpret the inconsistency of this finding with the traditional soluble dynamic equilibrium theory. The nanometre particles exist during surface tension interaction because of their small size. The traditional Ostwald-Freundlich relationship cannot apply to nanometre sizes, as it does not include the interface dispersion force interaction.
  • Keywords
    cobalt compounds; nanoparticles; solubility; surface tension; Co3O4; H2O; high-purity water; interface dispersion force interaction; monodispersed nanoparticle solubility; surface tension interaction; traditional Ostwald-Freundlich relationship; traditional soluble dynamic equilibrium theory;
  • fLanguage
    English
  • Journal_Title
    Micro & Nano Letters, IET
  • Publisher
    iet
  • ISSN
    1750-0443
  • Type

    jour

  • DOI
    10.1049/mnl:20080055
  • Filename
    4805250