Title :
Analysis of small area interdigtiated back contact silicon solar cells: The influence of boron diffusion process on cell performances
Author :
Shu Yen Liu ; Yun Kuo Tsao ; Zong Liang Yao ; Bo Shen Lee ; Kuang Chieh Lai ; Yu Pan Pai ; Chun Wen Lai
Author_Institution :
Motech Ind., Tainan, Taiwan
Abstract :
Twenty five small area (4 cm2) interdigitated back contact silicon solar cells have been fabricated and analyzed within one n-type Czochralski wafer. Although these cells made by an identical process, there is a large distribution of cell efficiencies. The absolute efficiency difference between the best cell and the worst cell is 4.38 %. We found that the distribution of the cell efficiencies is correlated with VOC and pseudo fill factor (pFF). The photoluminescence lifetime map shows a particular pattern of the boron diffused monitor wafer. This PL lifetime map has strong link to the distribution of the conversion efficiencies of the cells within the wafer. The lifetime map shows that the lifetime is higher of the center wafer than that of the edge wafer. Consequently, compared with the edge cells the cells in the center of the wafer have higher efficiencies. Besides, the bulk lifetime degraded significantly after the high temperature boron diffusion that may cause the higher J01 and lower VOC. According to this investigation, an optimal process condition for boron diffusion to reach a uniform boron dopant within the wafer and to avoid the bulk lifetime degradation is the critical point for high efficiency full-area IBC cells.
Keywords :
boron; elemental semiconductors; photoluminescence; silicon; solar cells; B; PL lifetime map; boron diffused monitor wafer; bulk lifetime degradation; cell efficiencies; cell performances; edge cells; edge wafer; high efficiency full-area IBC cells; high temperature boron diffusion process; n-type Czochralski wafer; pFF; photoluminescence lifetime map; pseudofill factor; small area interdigtiated back contact silicon solar cell analysis; Monitoring; Photoluminescence; Silicon; boron; charge carrier lifetime; diffusion processes; photoluminescence; photovoltaic cells; silicon;
Conference_Titel :
Photovoltaic Specialist Conference (PVSC), 2014 IEEE 40th
Conference_Location :
Denver, CO
DOI :
10.1109/PVSC.2014.6925440