Coarsening of the Nanolamellar Structure in a Soft Magnetic Alloy

Crystallization from a cobalt base Co₆₅Si₁₅B ₁₄Fe₄Ni₂ amorphous magnetic alloy yielded an interesting highly modulated nanolamellar structure with lamellar spacing of about 5 nm. Coarsening of this structure was investigated using X-ray diffraction (XRD), transmission electron microscopy (TEM), convergent beam electron diffraction (CBED), and X-ray electron dispersive spectrum (XEDS) techniques and was found to initiate at grain boundaries, which provided nucleation sites for equilibrium phases. Rod-shaped Co₂B precipitates were observed along the nanolamellae; such precipitates also played a role in coarsening. A coarse lamellar structure subsequently developed which eventually broke up into equiaxed grains. A metastable Co₃Si phase was also observed to form by an allotropic transformation. The coarsening of the nanolamellar structure was found to occur largely by discontinuous coarsening processes. The crystallographic relationship between the equilibrium and metastable phases was determined